Please use this identifier to cite or link to this item: https://hdl.handle.net/11681/5860
Title: Low-temperature phases of interfacial water in clay-water systems
Authors: Anderson, Duwayne M. (Duwayne Marlo), 1927-
Tice, A. R. (Allen R.)
Keywords: Adsorbed water
Clay minerals
Differential thermal analysis
Frost heave
Frozen soils
Frozen ground
Soils
Liquid phases
Phase transformations
Soil water
Soil moisture
Publisher: Cold Regions Research and Engineering Laboratory (U.S.)
Engineer Research and Development Center (U.S.)
Series/Report no.: Research report (Cold Regions Research and Engineering Laboratory (U.S.)) ; 290.
Description: Research Report
Abstract: Low temperature differential thermal analyses of selected clay-water systems were made to locate important phase change temperatures and to define fruitful temperature-pressure fields for precise calorimetric investigation. In addition to an exotherm corresponding to initial freezing, one, two or three exotherms were observed between -35°C and -60°C. The low temperature exotherms do not depend critically upon water content, but clearly they are related to clay mineral and exchangeable cation type. The evolution of heat in this temperature range probably corresponds to a phase change in the interfacial water.
Rights: Approved for public release; distribution is unlimited.
URI: http://hdl.handle.net/11681/5860
Appears in Collections:Research Report

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