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https://hdl.handle.net/11681/5860
Title: | Low-temperature phases of interfacial water in clay-water systems |
Authors: | Anderson, Duwayne M. (Duwayne Marlo), 1927- Tice, A. R. (Allen R.) |
Keywords: | Adsorbed water Clay minerals Differential thermal analysis Frost heave Frozen soils Frozen ground Soils Liquid phases Phase transformations Soil water Soil moisture |
Publisher: | Cold Regions Research and Engineering Laboratory (U.S.) Engineer Research and Development Center (U.S.) |
Series/Report no.: | Research report (Cold Regions Research and Engineering Laboratory (U.S.)) ; 290. |
Description: | Research Report Abstract: Low temperature differential thermal analyses of selected clay-water systems were made to locate important phase change temperatures and to define fruitful temperature-pressure fields for precise calorimetric investigation. In addition to an exotherm corresponding to initial freezing, one, two or three exotherms were observed between -35°C and -60°C. The low temperature exotherms do not depend critically upon water content, but clearly they are related to clay mineral and exchangeable cation type. The evolution of heat in this temperature range probably corresponds to a phase change in the interfacial water. |
Rights: | Approved for public release; distribution is unlimited. |
URI: | http://hdl.handle.net/11681/5860 |
Appears in Collections: | Research Report |
Files in This Item:
File | Description | Size | Format | |
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CRREL-Research-Report-290.pdf | 972.42 kB | Adobe PDF | View/Open |