Please use this identifier to cite or link to this item: https://hdl.handle.net/11681/30641
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dc.contributor.authorMedina, Victor F.-
dc.contributor.authorWaisner, Scott A.-
dc.contributor.authorMartinez-Guerra, Edith, 1989--
dc.contributor.authorJohnson, Jared L.-
dc.contributor.authorBrame, Jonathon A.-
dc.contributor.authorGao, Elizabeth J.-
dc.contributor.authorPage, Martin A.-
dc.date.accessioned2018-12-04T19:42:56Z-
dc.date.available2018-12-04T19:42:56Z-
dc.date.issued2018-11-
dc.identifier.govdocERDC TR-18-19-
dc.identifier.urihttp://hdl.handle.net/11681/30641-
dc.identifier.urihttp://dx.doi.org/10.21079/11681/30641-
dc.descriptionTechnical Report-
dc.description.abstractA technical evaluation of a capability to treat and/or recycle the effluent from the Army’s aqueous based chemical, biological, radiological and nuclear (CBRN) decontamination operations was conducted on 26–28 June 2017 at the U.S. Army Engineer Research and Development Center (ERDC) Waterways Experiment Station (WES), 3909 Halls Ferry Rd, Vicksburg, MS. The Decontamination Effluent Treatment System (DETS) is a reactor system specifically designed to address decontamination effluent. The objectives of the evaluation were to show an ability to reduce chemical hazards, reduce logistical burdens, and eliminate possible political impacts. The DETS is a fully functional system designed to treat waters containing contaminants, minimize decontamination water requirements, be rapidly deployable and easy to maintain, while minimizing the volume of decontamination waste requiring management/disposal. The field evaluation consisted of a simulation of vehicle decontamination followed by on-site treatment of the resulting effluent water.en_US
dc.description.sponsorshipEnvironmental Quality and Installations Research Program (U.S.)en_US
dc.description.tableofcontentsAbstract .......................................................................................................................................................... ii Figures and Tables ........................................................................................................................................ vi Preface ........................................................................................................................................................... ix Unit Conversion Factors ...............................................................................................................................x Acronyms and Abbreviations ..................................................................................................................... xi 1 Introduction ............................................................................................................................................ 1 1.1 Purpose of Study ............................................................................................................. 1 1.2 Decontamination wastewater ........................................................................................ 1 1.2.1 Decontamination ...................................................................................................................... 1 1.2.2 Environmental constituents ..................................................................................................... 3 1.2.3 Treatment chemicals ............................................................................................................... 3 1.2.4 CBRN agents ............................................................................................................................ 6 1.3 Treatment goals .............................................................................................................. 8 1.3.1 OCONUS .................................................................................................................................... 9 1.3.2 CONUS ...................................................................................................................................... 9 1.4 Current treatment systems for environmentally released CBRN agents ................... 10 1.4.1 Existing Army water treatment systems ................................................................................ 10 1.4.2 Old “O” Field remediation system.......................................................................................... 11 1.4.3 Treatment of contaminated water in the field ...................................................................... 12 1.5 Objectives ...................................................................................................................... 12 1.6 Approach ....................................................................................................................... 13 1.7 Scope ............................................................................................................................. 13 2 Design and Preliminary Testing of the Treatment System ......................................................... 14 2.1 Overview of design ........................................................................................................ 14 2.2 Sizing of the system ...................................................................................................... 14 2.3 Treatment unit processes ............................................................................................. 15 2.4 Pump and tubing .......................................................................................................... 15 2.5 Electrical system ........................................................................................................... 16 2.6 Control system .............................................................................................................. 18 2.7 Integrated system ......................................................................................................... 19 2.8 Unit processes .............................................................................................................. 21 2.8.1 Settling .................................................................................................................................... 21 2.8.2 Media filters ............................................................................................................................ 22 2.8.3 Reverse osmosis process ...................................................................................................... 23 2.9 Maintenance ................................................................................................................. 25 2.10 System costs, size & weight ......................................................................................... 25 3 Simulated Decontamination Operation .......................................................................................... 27 3.1 Location ......................................................................................................................... 27 3.2 Overview of the field evaluation ................................................................................... 27 3.3 Vehicle washing ............................................................................................................ 28 3.4 Collection of wash water .............................................................................................. 31 3.5 Spiking collected wash water ....................................................................................... 32 3.6 Treatment of wash water using DETS .......................................................................... 32 3.7 Sampling ....................................................................................................................... 32 4 Analytical Methods ............................................................................................................................. 34 4.1 Malathion quantification based on phosphate analysis ............................................ 34 4.2 Chlorine ......................................................................................................................... 35 5 Background Testing ........................................................................................................................... 36 5.1 Evaluation of treatment approaches that were not included in the pilot-scale DETS design ........................................................................................................ 36 5.1.1 Surfactant skimmer testing ................................................................................................... 36 5.1.2 Chemical degradation of bleach ........................................................................................... 37 5.1.3 Ultraviolet degradation of bleach .......................................................................................... 38 5.1.4 Ultrafiltration .......................................................................................................................... 40 5.2 Testing of settling tank ................................................................................................. 40 5.3 Testing of unit processes .............................................................................................. 41 5.3.1 Scaled column testing of the media filters ........................................................................... 41 5.3.2 Flat plate reactor evaluation of reverse osmosis ................................................................. 44 5.3.3 RO System .............................................................................................................................. 47 5.4 Laboratory testing of complete system ....................................................................... 48 6 Results of the Field Evaluation ......................................................................................................... 49 6.1 Assessment of the simulated decontamination effort ............................................... 49 6.2 Assessment of DETS operation .................................................................................... 49 6.2.1 Set up ...................................................................................................................................... 49 6.2.2 Operation ................................................................................................................................ 49 6.2.3 Problems ................................................................................................................................. 50 6.3 Analytical results of influent and treated water .......................................................... 52 6.3.1 Washed off components from vehicles ................................................................................. 52 6.3.2 Treatment chemicals ............................................................................................................. 56 6.3.3 Contaminants ......................................................................................................................... 58 6.3.4 Treatment summary ............................................................................................................... 60 7 Discussion ............................................................................................................................................ 62 7.1 Capture of decontamination wash water .................................................................... 62 7.2 System set-up and operation ....................................................................................... 62 7.3 Treatment of constituents ............................................................................................ 63 7.3.1 Environmental constituents ................................................................................................... 63 7.3.2 Decontamination chemicals .................................................................................................. 66 7.3.3 Chemical warfare simulants .................................................................................................. 66 7.4 Concentrate ................................................................................................................... 68 7.5 Monitoring ..................................................................................................................... 69 7.5.1 Discharge and reuse .............................................................................................................. 72 7.5.2 Analysis of wash water reuse ................................................................................................ 72 7.6 DETS Transportation ..................................................................................................... 74 7.7 Feedback from invited stakeholders ........................................................................... 75 8 Future Evaluations of the DETS ........................................................................................................ 77 9 Conclusions .......................................................................................................................................... 78 References ................................................................................................................................................... 79 Appendix A: Public Affairs Storyboard Prepared on DETS Field Evaluation ................................... 84 Appendix B: Specification Sheets on the Bredel 40 Pump (no endorsement implied) ................ 85 Appendix C: Specifications on Kubota Generator used in the study (no endorsement implied) ................................................................................................................................................. 87 Appendix D: Specification Sheet for Fold-a-Tank (no endorsement implied) ................................. 91 Appendix E: Technical Specification Documents on Sand and Anthracite Used in Sand Media Bed (no endorsement implied) ............................................................................................ 92 Appendix F: Operating Manual for the Reverse Osmosis System (first six pages, no endorsement implied) ........................................................................................................................ 96 Appendix G: List of Stakeholder Participants who attended the DETS Field Evaluation .......... 101 Appendix H: Notes Collected from the Stakeholder Discussion immediately following the DETS Field Evaluation (Brame and Medina) ........................................................................ 106 Appendix I: Report on the DETS Field Evaluation Prepared by Mr. Howard Beardsley, JPEOCBD ............................................................................................................................................ 110 Report Documentation Page-
dc.format.extent131 pages / 21.25 Mb-
dc.format.mediumPDF/A-
dc.language.isoen_USen_US
dc.publisherEnvironmental Laboratory (U.S.)en_US
dc.publisherConstruction Engineering Research Laboratory (U.S.)en_US
dc.publisherEngineer Research and Development Center (U.S.)en_US
dc.relation.ispartofseriesTechnical Report (Engineer Research and Development Center (U.S.)) ; no. ERDC TR-18-19-
dc.rightsApproved for Public Release; Distribution is Unlimited-
dc.sourceThis Digital Resource was created in Microsoft Word and Adobe Acrobat-
dc.subjectBiological decontamination--Sewageen_US
dc.subjectRadioactive decontamination--Sewageen_US
dc.subjectDecontamination (from gases, chemicals, etc.)--Sewageen_US
dc.subjectSewage--Purificationen_US
dc.titleSimulated vehicle decontamination and field evaluation of the Decontamination Effluent Treatment System (DETS), 27 June 2017, and associated background studiesen_US
dc.typeReporten_US
Appears in Collections:Technical Report

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